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Titanite (CaTiSiO5) is a commonly occurring and versatile accessory mineral with broad applications in petrochronology. In situ U-Pb and trace element analyses via SIMS and LA-ICPMS are routinely performed using a matrix-matched reference material for U-Pb and standard glasses (non-matrix matched reference material) for elemental abundance determination. We report U-Pb isotopic ratios and major and trace element concentrations for three titanite samples (Ecstall, McClure and FCT) which are commonly used as reference materials in petrochronology studies. In addition, we characterize two new samples which can potentially serve as matrixmatched reference materials for titanite trace element geochemistry (BLR-2 and BRA-1). Based on electron microprobe analysis, samples BLR-1 and BLR-2 are homogeneous and suitable for use as a primary reference material for trace element concentrations. Whereas Ecstall, McClure, and FCT titanite reference materials show high intra-grain heterogeneity, yielding relative standard deviations for most trace elements between 5% and 40%, with higher standard deviations for U of 70% for Ecstall (n = 26), 265% for McClure (n = 22), and 202% for FCT (n = 26). Therefore, we suggest that these grains are unsuited to serve as reference materials for trace element quantification. The BRA-1 titanite has low trace element concentrations and is chemically heterogeneous (total REE abundances of 40 ppm for the rim and 95 ppm for the core of the grain), thus is not suitable for standardization of chemical composition using LA-ICPMS. It is commonly asserted that a matrix-matched standardization provides a more robust downhole fractionation correction compared to a non-matrix matched standardization. However, it remains unclear which standardization approach (matrix-matched vs non-matrix matched/glass) is more accurate for titanite trace element quantification. To resolve this, we tested several standardization approaches for trace element quantification, comparing matrix-matched (BLR-1) and nonmatrix- matched (NIST612) standardizations with different internal elemental standards (IES; Ca, Si and Ti) and without internal standardization (semi-quantitative). To provide an independent constraint on the accuracy of the various trace element standardization techniques we compared results to trace element concentrations obtained via solution Q-ICPMS on crushed BLR-2 and BRA-1 aliquots. The matrix-matched standardization using Si as the IES yields the best reproducibility of trace element concentrations followed by the matrix-matched reduction using Ti as the IES. Moreover, the matrix-matched semi-quantitative correction yielded the lowest weighted percentage of difference compared to reference trace composition quantified by solution ICPMS. Finally, in this contribution we also benchmark sampling-size for precise U-Pb dating of common-Pb rich phases like titanite. 

Abstract The plate-boundary conditions of the Mesozoic North American Cordillera remain poorly constrained, but most studies support large (>800 km) southward motion of the Insular and Intermontane superterranes during Jurassic–Cretaceous time. An implicit feature in these models of large coastwise displacements is the presence of one or more continentalscale sinistral strike-slip faults that could have dismembered and displaced terrane fragments southward along the western margin of North America prior to the onset of mid-Cretaceous shortening and dextral strike-slip faulting. In this study, we documented a system of sinistral intra-arc shear zones within the Insular superterrane that may have accommodated large southward motion. Employment of a new large-n igneous zircon U-Pb method more than doubled the precision of measurements obtained by laser ablation–inductively coupled plasma–mass spectrometry (from ~1% to 0.5%) and allowed us to demonstrate the close temporal-spatial relationship between magmatism and deformation by dating comagmatic crosscutting phases. Crystallization ages of pre-, syn-, and postkinematic intrusions show that the intra-arc shear zones record an Early Cretaceous phase of sinistral oblique convergence that terminated between 107 and 101 Ma. Shear zone cessation coincided with: (1) collapse of the Gravina basin, (2) development of a single voluminous arc that stitched the Insular and Intermontane superterranes together, and (3) initiation of eastwest contractional deformation throughout the Coast Mountains. We interpret these concurrent tectono-magmatic events to mark a shift in plate kinematics from a sinistral-oblique system involving separate terranes and intervening ocean basins to a strongly convergent two-plate margin involving a single oceanic plate and the newly assembled western margin of North America. 

Abstract The southern Coast Mountain batholith was episodically active from Jurassic to Eocene time and experienced four distinct high magmatic flux events during that period. Similar episodicity has been recognized in arcs worldwide, yet the mechanism(s) driving such punctuated magmatic behavior are debated. This study uses zircon Hf and O isotopes, with whole-rock and mineral geochemistry, to track spatiotemporal changes in southern Coast Mountains batholith melt sources and to evaluate models of flare-up behavior and crust formation in Cordilleran arc systems. Zircon Hf isotope analysis yielded consistently primitive values, with all zircon grains recording initial εHf between +6 and +16. The majority (97%) of zircons analyzed yielded δ18O values between 4.2‰ and 6.5‰, and only five grains recorded values of up to 8.3‰. These isotopic results are interpreted to reflect magmatism dominated by mantle melting during all time periods and across all areas of the southern batholith, which argues against the periodic input of more melt-fertile crustal materials as the driver of episodic arc magmatism. They also indicate that limited crustal recycling is needed to produce the large volumes of continental crust generated in the batholith. Although the isotopic character of intrusions is relatively invariant through time, magmas emplaced during flare-ups record higher Sr/Y and La/Yb(N) and lower zircon Ti and Yb concentrations, which is consistent with melting in thickened crust with garnet present as a fractionating phase. Flare-ups are also temporally associated with periods when the southern Coast Mountains batholith both widens and advances inboard. We suggest that the landward shift of the arc into more fertile lithospheric mantle domains triggers voluminous magmatism and is accompanied by magmatic and/or tectonic thickening. Overall, these results demonstrate that the magmatic growth of Cordilleran arcs can be spatially and temporally complex without requiring variability in the contributions of crust and/or mantle to the batholith. 

Abstract The timing of crustal thickening in the northern Central Andean Plateau (CAP), at 13–20°S, and its relationship to surface uplift is debated. Zircon qualitatively records crustal thickness as its trace element chemistry is controlled by the growth of cogenetic minerals and relative uptake of light and heavy Rare Earth Elements. Jurassic to Neogene zircons from volcanic rocks, sandstones, and river sediments reveal shifts in trace element ratios suggesting major crustal thickening at 80–55 Ma and 35–0 Ma, coincident with high‐flux magmatism. An intervening magmatic lull due to shallow subduction obscures the magmatic record from 55 to 35 Ma during which thickening continued via crustal shortening. Protracted thickening since the Late Cretaceous correlates with early elevation gain of the CAP western margin, but contrasts with Miocene establishment of near modern elevation in the northern CAP and the onset of hyperaridity along the Pacific coast, highlighting their complex spatial and temporal relationship.